The target complex Bis-yd zinc ( II) iodide has been synthesized and characterized by X-ray single-crystal structure analysis. 合成了目标配合物:碘化双[3,4二甲氧基苯甲醛缩氨基硫脲]合锌(II),其结构通过单晶X射线衍射法确定。
Mechanistic Insights into the Opening of β-Pinene Epoxides with Trimethylsilyl Cyanide-zinc Iodide 三甲基硅腈-碘化锌对β-蒎烯环氧化物的开环反应机理
2, 10-oxido-10 β-pinane and 2, 10-oxido-10 α-pinane reacted with trimethylsilyl cyanide separately in the presence of zinc iodide to produce a same complex mixture of products. 2,10-环氧-10β-蒎烷和2,10-环氧-10α-蒎烷在碘化锌存在下,分别与三甲基硅腈反应,生成同样组分的产物混合物。
The intermolecular cyclotrimerization reaction was easy to handle and carried out under mild conditions. Furthermore, nickel catalyzed intermolecular cyclotrimerization reaction of alkynes in the presence of nitrogen ligands and zinc iodide was studied and a newfashioned nickel catalytic system was exploited. 该催化体系用于环三聚反应具有操作简单、条件温和等优点。我们研究了氮配体和ZnI2参与的镍催化的单炔的环三聚反应,并开发了一类新型的镍催化体系。